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Storing urea solutions long-term — the bottle, the temperature, the contamination problem

August 19, 2024·7 min read·By Maya Trousdale
ureaDEFchemistry

Diesel exhaust fluid (DEF, 32.5% urea in deionized water) and agricultural urea solutions look chemically similar but the spec tolerances differ wildly. DEF has tight purity requirements (ISO 22241) and any trace contamination poisons SCR catalysts in diesel engines. Ag urea is more forgiving. The tote handles both; the difference is in how you operate it.

DEF in totes

DEF totes need to be virgin-dedicated — any previous fluid history is a contamination risk. The major suppliers (Yara, BASF, BlueDEF) ship new totes for DEF and don’t reuse them across other services. We do not sell used totes into DEF service for this reason; the contamination liability is too high and the receiving market won’t accept reconditioned units regardless of wash protocol.

If you operate a DEF reseller business, source new totes only, dedicate them to DEF service forever, and dispose of them at end-of-life. The total cost is higher but the alternative is potential warranty claims from end customers.

Ag urea

Agricultural urea solutions (28–32% urea, or starter blends with urea) are tote-friendly and we sell into this market routinely. Used totes that previously held urea, UAN, or related fertilizers are fine for continued ag urea service. The bottle holds up; the cage corrodes faster than non-fertilizer service.

Crystallization at cold

Urea solutions crystallize below their salt-out temperature, similar to UAN. DEF salts out around 12°F (which is why DEF tanks on diesel trucks have heaters); ag urea solutions are similar. Winter storage of any urea solution outdoors in the Midwest requires either insulation, heat, or acceptance of a remelt cycle.

Trace contaminant sources

Even for ag urea, the contaminants that show up in receiving lab tests are usually: trace minerals from rinse water, ferric ion from galvanized hardware in contact, and biological growth (algae, bacteria) from previous biological residue. The first is solved by potable rinse only; the second by stainless hardware on dedicated lines; the third by hot-caustic wash protocol.

Bottle inspection

Urea solutions are slightly biocidal at field concentration, so biofilm growth inside the bottle is rare. The more common inspection issue is bottom-valve gasket swelling, which happens slowly with sustained exposure. Replace gaskets at every wash cycle if the tote is in continuous urea service.

Questions on this one? Email info@ibctankscleveland.com. We answer everything inside one business day — usually inside four hours.

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